段正超，男,，博士,，教授,，碩士研究生導(dǎo)師

研究方向：不對(duì)稱催化及藥物合成

Email: [email protected]

主講課程：有機(jī)化學(xué),、藥物合成反應(yīng),、有機(jī)波譜解析

一,、教育與研究經(jīng)歷

1993.09-1997.07 西南民族大學(xué)化學(xué)系,，應(yīng)用化學(xué)專業(yè),，獲學(xué)士學(xué)位

1997.07-今 湖北民族大學(xué)（原湖北民族學(xué)院）化學(xué)與環(huán)境工程學(xué)院,，從事教學(xué)及科研工作

2002.09-2005.09 中科院大連化學(xué)物理研究所，有機(jī)化學(xué)專業(yè),，獲理學(xué)碩士學(xué)位

2006.09-2009.12 中科院大連化學(xué)物理研究所,，有機(jī)化學(xué)專業(yè)，獲理學(xué)博士學(xué)位

二,、主持科研項(xiàng)目

(1) 2013.1-2016.12,，新型手性P/N配體的設(shè)計(jì)合成及不對(duì)稱催化性能研究，國(guó)家自然科學(xué)基金委,，50萬(wàn)元

(2) 2011.1-2012.12,，新型手性P/S配體的設(shè)計(jì)合成及其在不對(duì)稱催化中的應(yīng)用研究，教育部,，10萬(wàn)元

(3) 2011.1-2012.12,，新型手性P/S配體的設(shè)計(jì)合成及其應(yīng)用研究，湖北省教育廳,，2萬(wàn)元

(4) 2011.1-2012.12,，基于三唑雜環(huán)骨架的手性P/S配體的設(shè)計(jì)、合成及不對(duì)稱催化性能研究,，湖北民族學(xué)院,，2萬(wàn)元

(5) 2011.1-2012.12，新型手性N,N,P三齒配體的設(shè)計(jì)合成及應(yīng)用研究,，湖北民族學(xué)院,，2萬(wàn)元

三、主要代表性成果

1. 張華林,，郭志謀,，王聯(lián)芝,，金高娃，鄒麗紅,，呂園園,，馬明輝，閆競(jìng)宇*,，段正超*,，梁鑫淼.  基于電噴霧-四極桿-飛行時(shí)間質(zhì)譜的神經(jīng)節(jié)苷脂的結(jié)構(gòu)解析.  分析化學(xué). 2019, 47(06):  925-932.

2. Zheng-chao Duan*, Lian-zhi Wang, Xin-jian Song, Xiang-ping Hu, Zhuo Zheng. Enantioselective synthesis of optically active alkylphosphonates via Rh-catalyzed asymmetric hydrogenation of beta-substituted alfa,beta-unsaturated phosphonates. Tetrahedron:Asymmetry 2012,23, 508–514.

3. Zhengchao Duan*, Lianzhi Wang, Xiaoyu Zuo, Xiangping Hu, Zhuo Zheng. Rh-ImiFerroPhos complexes catalyzed asymmetric hydrogenation of beta-substituted α,β-unsaturated phosphonates.Chinese Journal of Catalysis 2014, 35, 227–231.

4. 段正超*，王聯(lián)芝,，胡向平,，鄭 卓.衍生于手性雙二茂鐵乙胺的單齒亞磷酰胺配體在不對(duì)稱催化氫化中的應(yīng)用.分子催化，2012,26,328-332.

5. 段正超*,，王聯(lián)芝,，左曉宇，屈桃李,，胡向平,，鄭 卓. WalPhos配體/銠配合物對(duì)β，γ-不飽和膦酸酯的不對(duì)稱催化氫化.應(yīng)用化學(xué),，2014, 31, 242-244.

6. Duan Zhengchao*, Wang Lianzhi, Qu Taoli, Zuo Xiaoyu, Hu Xiangping, Zheng Zhuo. Enantioselective Synthesis of Chiral 2-Phenylpropanol via Rh-catalyzed Asymmetric Hydrogenation of 2-Phenylprop-2-en-1-ol.應(yīng)用化學(xué),，2014, 31, 1356-1358.

7. Zheng-Chao Duan, Xiang-Ping Hu*, Dao-Yong Wang, Jia-Di Huang, Sai-Bo Yu, Jun Deng, Zhuo Zheng*. Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands.Adv. Synth. Catal.2008,350, 1979-1983.

8. Zheng-Chao Duan, Xiang-Ping Hu*, Cheng Zhang, Dao-Yong Wang, Sai-Bo Yu, Zhuo Zheng*. Highly Enantioselective Rh-Catalyzed Hydrogenation of beta,gama-Unsaturated Phosphonates with Chiral Ferrocene-based Monophosphoramidite Ligands.J. Org. Chem.2009,74, 9191-9194.

9. Zheng-Chao Duan, Xiang-Ping Hu*, Jun Deng, Sai-Bo Yu, Dao-Yong Wang, and Zhuo Zheng*.Asymmetric synthesis of chiral glutaric acid derivatives via Rh-catalyzed enantioselective hydrogenation.Tetrahedron: Asymmetry2009,20, 588-592.

10. Zheng-Chao Duan, Xiang-Ping Hu*, Dao-Yong Wang, Sai-Bo Yu, Zhuo Zheng*. Cu-catalyzed asymmetric conjugate reduction of beta-substituted alfa,beta-unsaturated phosphonates: an efficient synthesis of optically active beta-stereogenicalkanephosphonates.Tetrahedron Lett.2009,50, 6720-6722.

        11. DUAN Zhengchao, HU Xiangping, ZENG Qingheng, ZHENG Zhuo*. Enantioselective Addition of Phenylacetylene to Aldehydes Using a Planar Chiral N,O-Ferrocene Ligand.Chinese Journal of Catalysis2005,26, 352-354.